Peningkatan Senyawa Anti Bacterial Geraniol pada Citronella Oil Sebagai Bahan Baku Pembuatan Perfume Anti-Bacterial
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Abstract
Research is underway to increase the geraniol content of citronella oil by vacuum distillation. Geraniol is a fragrance compound approved by IFRA (International Fragrance Association) and can be used in the formulation of antibacterial perfumes. However, the levels of geraniol in citronella oil are still relatively low. The processing of fragrant citronella oil can be improved by increasing the geraniol content through vacuum distillation. This can be achieved by varying the pressure between 1 and 8 mbar and operating times between 20 and 60 minutes to the final boiling point. The resulting samples were analysed by GC-MS, FT-IR, refractive index and bacterial testing. The results indicate that lower pressure levels can increase geraniol levels. The geraniol content increased by a maximum of 80.11% at a pressure of 1 mbar during the Final Boiling Point operation, with a refractive index of 1.501. FTIR showed an intense broad peak in the range of 2200-3200 cm-1, particularly at 3086.98cm-1, indicating the presence of the OH hydroxyl polymer group in geraniol. The study successfully increased the geraniol content from 20.32% to 80.11%. The results of the antibacterial perfume test showed greater antibacterial activity against Staphylococcus Aerus strains compared to E. coli. The inhibition diameter was 10.13 mm after 48 hours.
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References
Sarkic, A., & Stappen, I. (2018). Essential oils and their single compounds in cosmetics—acritical review. Department of Pharmaceutical Chemistry.1-21.
Alberto, C., Marin, L.N., Unidad, A., & Amparo, S. (2018). Perfumes. Encyclopedia of Analytical Science, 3rd Edition, Hal 1-6..
Bota Arancibia, Y., Mirari, M. Elvir, L.-C., Carmen,G., & Montero, P. (2014). Release of volatile compounds and biodegradability of active soyprotein lignin blendfilms with added citronella essential oil. Food Control 44 (2014) 7-15. [4] A. U. Zaman, “A comprehensive review of the development of zero waste management : lessons learned and guidelines,” J. Clean. Prod., pp. 1–14, 2014.
Chen, W.A,. & Viljoen, M. (2010). Geraniol- a review of a commercially important fragrance material. South. African Journal of Botany 76 (2010) 643-651.
Keila, L,. Yagmur, Y., Zevallos, C., Kerth, M.A., & Thomas, M.T. (2018). Geraniol-loaded polymeric nanoparticles inhibit enteric’pathogens on spinach during posttreatment refrigerated and temperature abuse storage. February 2018 | Volume 2 | Article 4.1-14
Beneti, S,. Eline, R,. Marcos, L C., Caren, D., Frizz, D. L., & Vladimir, J.O. (2011). Fractionation of citronella (Cymbopogon winterianus) essential oil and concentrated orange oil phase by batch vacuum distillation. Journal of Food Engineering 102 (2011) 348–354
Machmud, L. (2013). Peningkatan Kadar Eugenol Pada Minyak cengkeh dengan Metode Saponifikasi-Distilasi Vakum. Jurnal Teknologi Kimia dan Industri, volume 2. nomor 2. halaman 198-203 [9] Kementerian Pekerjaan Umum, Materi Bidang Sampah I, Diseminasi dan Sosialisasi Keteknikan Bidang PLP. Jakarta, Indonesia: Ditjen Cipta Karya, 2013.
Widi, A,. & Putra, N.N. (2014). Peningkatan Kadar Geraniol Kadar Geraniol Dalam Minyak Sereh Wangi (Citronella Oil) dan Aplikasinya sebagai bio Additive Gasoline). Jurnal Alam Terbarukan, Vol 3, Edisi ISSN :2303-0623. 1-5195-196.
Timung, R., Chitta, R.B., Sukumar, P., Vaibhav, V., & Gouda. (2016). Composition and anti-bacterial activity analysis of citronella oil obtained by hydrodistillation: Process optimization study. Industrial Crops and Products. 94 (2016) 178–188.
Wany, A., Kumar, A., Nallapeta, S., Jha, S., Nigam, V.K., & Pandey, D.M. (2014). Extraction and characterization of essential oil components based on geraniol and citronellol from java citronella .
Simoent, T., Gabriel, A., Fransisco, G-C., & Rodrigo, N. (2017). Direct transesterification of microalgae biomass and biodiesel refining with vacuum distillation. Algal Research 28 (2017) 30–38.
Lin, Y., Jingru, L., Wanwen, C., Xiaoli, L., Qixing, J., & Wenshui, X. (2017). Geraniol grafted chitosan oligosaccharide as a potential antibacterial agent. Carbohydrate Polymer 356-364.
Lapczynski, A., Bhata, P.T,. Foxenberg, R.J,. Letizia, C.S,. & Api, M. (2008). Fragrance material review on geraniol. Food and Chemical Toxictology S160-S170.
[BSN] Badan Standar Nasional. 1995. Standar mutu minyak sereh wangi SNI 06-3953-1995. Jakarta.